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Please use this identifier to cite or link to this item: https://dyhuir.dyhu.edu.tw/ir/handle/987654321/116

Title: Desferrioxamine β 更有效的合成法
Authors: 彭明玲
Keywords: 合成法;更有效
Date: 1988
Issue Date: 2011-08-08T07:05:21Z
Abstract: 這是生物鐵螫合物(microbial iron chelator) desferrioxamine B Hcl和類似物的合成法。對於dihydroxzmat, trihydroxamate, tetrahydroxamate 和其他 desferrioxamine 同屬物,此方法更適用於它們的合成。在合成過程中可得到1級胺氮(primary amino nitrogen)功能基的desferrioxamine。此合成過程最主要的是O-benzy1-N-(4-cyanobuty1) hydroxylamine它是由O-benzy1 hydroxylamine nitrogen 和 succinic 或 acetic anhydride acylated 來的。若以一系列高產率縮合和還原形成半酸醯胺(half acid amide)或醯(amide)結果可得 desferrioxamine 45%。desferrioxmine 45%。最後再以desferrioxamine 衍生物有效的合成法應用於合成 desferrioxamine desamine 類似物。
Relation: 德育學報第四期:075-084
Appears in Collections:[德育學報(1-18期)] 德育學報04期

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